As stated above "das" is the common demonstrative pronoun - independent of gender and number. You can thus say
Das sind meine Brüder.
And it would be the generic choice. But "der/die/das" is a demonstrative pronoun as well. So what you are seeing is technically not the definite article, but a pronoun that is identical to it! As a demonstrative pronoun alone "der/die/das" has 10 sub uses in my dictionary.
But I believe what you are interested in here is the contrasting use of the demonstrative "der".
I try to make an example where both "das" and "der" are used idiomatically, the first neutrally and the second for contrast:
Wer ist der Mann mit der Sonnenbrille?
Das ist mein Freund!
Und was ist mit Martin?
Der hat mich verlassen!
Translation:
Who is the man with the sun glasses?
That's my boyfriend!
And what about Martin?
He (contrasting) has left me!
More examples of "der/die/das" as a contrasting demonstrative pronoun include:
Welcher ist dein Vater? / Which one is your father?
Der mit der Glatze... / The one with the bald head.